• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    method for creping a paper net the present application presents a composition of material useful for producing very high degrees of flexibility of tissue paper; the material composition comprises an adhesive composition that includes a glycerol-based polyol; the glycerol-based polyol prevents the composition from becoming brittle and non-volatile; this allows the composition to become re-moistened after creping and allows strong levels of adhesion even at high temperatures.
    公开号:BR112012016478B1
    申请号:R112012016478-3
    申请日:2011-01-05
    公开日:2020-02-18
    发明作者:Gary S. Furman；Xiaojin Harry Li；Winston Su；Vladimir E. Grigoriev
    申请人:Nalco Company；
    IPC主号:
    专利说明:

    “METHOD FOR CREATING A PAPER NETWORK Cross Reference to Related Orders.
    None.
    Declaration Regarding Research or Development Sponsored by the Federal Government.
    Not applicable.
    Background of the Invention [0001] The present patent application relates to compositions of material and methods for using them to improve the physical properties of manufactured paper, in particular making a particularly flexible tissue paper. Typically, tissue paper obtains its characteristic properties, flexibility, volume, absorbency and ability to stretch, by a process involving a Yankee Dryer device. In normal manufacturing, paper is fed into the Yankee Dryer device as a network of moist fibers. The wet fiber web is dried in a compression cylinder where the sheet is transferred to the surface of a Yankee Dryer cylinder. At this point, the paper net typically has 35-40% consistency (65-60% water). The sheet is further dried by the Yankee Dryer steam-heated cylinder and hot air injection systems up to 90-98% consistency and removed with a scraper blade. The mechanical action of the scraper blade results in a break in the fiber connections that forms a microdraw structure that gives tissue paper its characteristic properties. This process is called creping.
    [0002] In order to properly crepe a paper net to make flexible tissue paper, the paper net has to adhere to the dryer cylinder surface
    Petition 870190036739, of 17/04/2019, p. 33/76
    2/20
    Yankee. When the paper net collides with the scraper blade, micro folds are formed in the direction of the machine by the action of compression or shortening while, at the same time, the net is separated from the dryer cylinder. This adhesion is facilitated by the application of an adhesive on the surface of the dryer cylinder. In addition, components that provide a wet finish can also contribute to the adhesion that occurs. The adhesives commonly used by Yankee are synthetic polymers such as polyaminoamide-epichlorohydrin (PAE) resins, polyamine-epichlorohydrin resins, polyvinyl alcohols, polyvinyl acetates, polyacrylamides, polyamines, polyvinylamines, polyamides, polyvinylpyrrolides, polyethylsolids, polyether and polyethylene, polyether polyethyls, polyether polyethyls, polyethylsolids, polyethyls, polyethyls, polyethyls and polyethyls. others described in US Patent 5,374,334. Other derivatized natural and natural polymers can also be employed, including starch, guar gum, carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose and similar materials. Various compounds with lower molecular weight, release agents, oils and surfactants are used to modify the properties of these adhesives.
    [0003] The fabric industry has a continuing interest in the manufacture of premium grade fabrics, which are fabrics with high levels of softness and volume. Improvements in softness can be obtained by modifying the fiber source, implementing particular formation and drying strategies, creping the fiber sheets and using the wet or topical application of softening agents. Creping the sheet of paper when it has a very low humidity level (<3%) is a very effective way to achieve the desired levels of softness and high volume. At low levels of
    Petition 870190036739, of 17/04/2019, p. 34/76
    3/20 moisture, the sheet and the coating tend to adhere to each other more strongly which makes the sheet peel off in the Z direction more efficiently, thereby generating greater volume and smoothness. Low humidity levels can be achieved by increasing the temperature of the Yankee dryer and injection systems.
    [0004] Despite the benefits to the fabric's softness, low humidity creping is not being widely practiced due to issues of coating performance. Conventional creping adhesives typically develop a hard coating that is less rewetchable after being subjected to high temperatures and extensive drying which is required for low humidity creping. This hard and brittle coating results in a loss of adhesion and also results in blade vibration (chatter), which can cause non-uniform creping, blade wear and, in extreme cases, damage the Yankee dryer cylinder surface.
    [0005] An attempt to address these problems is to use humectants to plasticize the adhesive and thereby combat many of the consequences of high temperatures in the Yankee Dryer. One of these humectants is glycerol (see, for example, US Patents 5,187,219 and 5,660,687). Glycerol has been shown to alter the viscoelastic properties of a coating film. In addition, it increases the glass transition temperature and the shear modulus of the film, making it softer and more rewetable in both high and low temperature conditions. Unfortunately, when in the diluted aqueous form, as is the case when applied to Yankee dryers, the volatility
    Petition 870190036739, of 17/04/2019, p. 35/76
    4/20 of glycerol / water mixtures limits the effectiveness of glycerol as a plasticizer. As water is also common in Yankee Dryer environments, there is a great demand for a modifying agent that plasticizes the film, but is not as volatile as glycerol. US 6547925 discloses the use of softening agents in creping adhesives to be spread on the surface of the Yankee dryer.
    Brief Summary of the Invention [0006] At least one application of the present application is directed to a creping method of a paper web comprising the steps of:
    a) applying, in a rotating creping cylinder, a coating composition, the coating composition comprising one or more adhesive agents, at least one release agent and at least one polyglycerol;
    b) pressing the paper net against the creping cylinder to adhere the paper net to the creping cylinder; and
    c) dislodging the paper net from the creping cylinder with a blade.
    [0007] The coating composition can remain plasticized at a temperature beyond the volatility limit of glycerol. Polyglycerol can be between 1 and 70% of the coating composition. The coating composition may have a glass transition temperature of less than 100 ° C. The coating composition can be readily rewetted after the paper has been dislodged from the creping cylinder.
    [0008] Polyglycerols can be selected from the group consisting of: polyglycerol according to
    Petition 870190036739, of 17/04/2019, p. 36/76
    5/20 with the formula:
    mnp 0H r where m, n, o, p, qer are equal to an integer from 0 to 25 polyglycerol formed by crosslinked glycerol with epichlorohydrin, base condensation polyglycerols, polymerization of glycidol-based monomers and any combination of them.
    [0009] The structure of polyglycerol can be selected from the group consisting of: linear, branched, hyper-branched, dendritic, cyclic or any combination of them. The polyglycerol can have a molecular weight greater than 100 g / mol. The coating may further comprise polyaminoamide-epichlorohydrin (PAE) resins, polyamine-epichlorohydrin resins, polyacrylamides, polyvinylamines, polyvinylpyrrolidones, natural polymers, derivatized natural polymers, starch, guar gum, carboxymethylcellulose, additives, hydroxyethyl cellulose, additives, hydroxyethyl cellulose, hydroxymethyl cellulose, additives, hydroxymethylcellulose, hydroxymethylcellulose, hydroxymethylcellulose. organic fatty chains of approximately 12 to approximately 22 carbon atoms, quaternary salts of dialkyl imidazoline, quaternary salts of dialkyl diamidoamine, quaternary salts of monoalkyl trimethylammonium, quaternary salts of dialkyl dimethylammonium, quaternary salts of trialkyl, quaternary, quaternary, quaternary, quaternary, quaternary, quaternary, quaternary, quaternary dialkyl and trialkyl ester, polysiloxane, quaternary silicones, organoreactive polysiloxanes,
    Petition 870190036739, of 17/04/2019, p. 37/76
    6/20 Amino-functional polydimethylsiloxanes, polyamines, polyamides, polyamidoamines, amidoamine-epichlorohydrin polymers, polyethyleneimines, polyvinyl alcohol, polyvinyl alcohol copolymers, polyvinyl acetate, copolymers of vinyl acetate, polyethers, copolymer, acid, polymers, acid polyols cellulose derivatives, starches, starch derivatives, animal glue, vinylamine / vinyl alcohol crosslinked polymers, glyoxalated acrylamide / diallyldimethylacrylamide copolymers, halogen-free creping cylinder adhesives based on polyaminoamide cationic crosslinked polymers and any combination thereof. The coating composition may further comprise lactic acid or lactate, may further comprise release agents, other modifiers (including phosphates) and functional additives, polyglycerols, polyglycerol derivatives and other glycerol based polyols and any combination thereof.
    [0010] The release agent may comprise an item selected from the group consisting of: release agents composed of naphthenic, paraffinic, vegetable, mineral or synthetic oil and emulsifying surfactants, release agents formulated with one or more surfactants such as fatty acids, alkoxylated alcohols, alkoxylated fatty acids and any combination thereof. The coating composition can be applied as an aqueous solution, an emulsion or a dispersion. The creped paper can be prepared according to the method of the present application.
    Brief Description of the Drawings [0011] A detailed description of this
    Petition 870190036739, of 17/04/2019, p. 38/76
    7/20 patent application is described hereafter with specific reference being made to the drawings in which:
    • figure 1 is an illustration of the structure of polyglycerols suitable for use in the film of the present patent application;
    • figure 2 is an illustration of the structures of suitable repeated units, which can be used in the polyglycerols used in the film of the present patent application;
    • figure 3 is a graph showing the improved volatility properties of the modifiers of the present application;
    • figure 4 is a graph showing the improved resistance to weight loss of diluted modifiers; and • figure 5 is a graph showing the improved strength of the dry film coating of the present application.
    Detailed Description of the Invention
    DEFINITIONS [0012] For the purposes of this request, the definition of these terms is as follows:
    • “Dispersion means a thermodynamically unstable mixture of extremely fine solid particles, typically of colloidal size, which are highly dispersed through a continuous liquid phase that is not otherwise mixable with it. The dispersions can be at least temporarily stabilized with dispersing agents.
    • “Emulsion means a thermodynamically unstable mixture of dispersed liquid phase, which is highly dispersed as small globules through a continuous liquid phase which,
    Petition 870190036739, of 17/04/2019, p. 39/76
    8/20 otherwise, it cannot be mixed with it. Emulsions can be at least temporarily stabilized with surfactants and emulsifiers.
    • “Polymeric Polyol means a polymer in which the monomeric repeating units comprising the polymer are at least partly polyols and include, but are not limited to, polyglycerols, polyglycerol derivatives and a polymer consisting of at least one monomeric unit of glycerol and at least one other monomeric unit from other multiple monomeric units regardless of the sequence of arrangements of monomeric units and any combinations thereof.
    • “Polyol means a compound or polymer containing at least two hydroxyl groups to which each of the at least two hydroxyl groups are attached to separate carbon atoms from an aliphatic skeleton, including, but not limited to, glycols, glycerol, pentaerythritol, trimethylolethane, trimethylolpropane, 1,2,6-hexanotriol, sorbitol, inositol, poly (vinyl alcohol) and glycerol-based polyols.
    • “Plasticizer means a substance that, when added to a material, causes an increase in the flexibility and handling of that material, often as a result of the decrease in the glass transition temperature of that material.
    [0013] If those definitions above or a definition presented somewhere in that request is inconsistent with a meaning (explicit or implicit) that is commonly used, in a dictionary, or presented in a source incorporated as a reference in that request, the terms of the request and the particular claim are
    Petition 870190036739, of 17/04/2019, p. 40/76
    9/20 understood as being interpreted according to the definition found in this application, and not according to the common definition, definition found in the dictionary, or the definition that has been incorporated as a reference.
    [0014] At least one application of the present application is directed to a Yankee Dryer coating composition comprising an adhesive, a release agent and a modifying agent. The adhesive attaches a sheet of paper to the drum surface of the Yankee Dryer. The present application for a patent covers applications for sheets of paper comprising cellulosic fibers, synthetic fibers and any combination thereof. The release agent reduces the strength of the adhesive to allow a scraper blade to remove the dry paper blade from the drum. The modifying agent plasticizes the coating composition, keeping it soft and allowing it to be re-moistened and maintain adhesion in the presence of high temperature. A description of the Yankee Dryer coating compositions is presented in US Patent Application 12/273217.
    [0015] In at least one application of the modifying agent is a composition comprising a glycerol-based polymeric polyol, including polyglycerols, polyglycerol derivatives and a polymer consisting of at least one monomeric unit of glycerol and at least another monomeric unit of other monomer units regardless of the sequence of arrangements of monomer units. The appropriate glycerol-based polymeric polyol includes, but is not limited to, those described in US Patent Application 12 / 582,827 and Published Patent Application
    Petition 870190036739, of 17/04/2019, p. 41/76
    10/20
    American 2009/0130006. In at least one application, the polymeric polyol has a molecular weight of less than 100.
    [0016] In at least one application, the modifying agent is a composition comprising polyglycerols. Suitable polyglycerols include, but are not limited to, those described in US Patent Application 12 / 582,827 and US Published Patent Application 2009/0130006. In at least one application, polyglycerol has a molecular weight greater than 100. Although glycerol is known to have some use as a plasticizer in other materials, for example, as described in U.S. Patent 5,187,219, no attempt has been made previously to use polyglycerol in coatings of the Yankee dryer.
    [0017] In at least one application, polyglycerol is selected from the list consisting of: diglycerol, triglycerol and larger analogs, as specified by the structure illustrated in FIG. 1. Polyglycerols can be prepared by crosslinking with epichlorohydrin, by condensing glycerol, by polymerizing glycidol-based monomers or any combination of them.
    [0018] In at least one application, polyglycerol may have a structure as illustrated in FIG. 1. Polyglycerol comprises a structure that includes at least two repeated units selected from at least one of the structures listed in FIG. 2 including, but not limited to, linear structures I and II, branched, hyper-branched or dendritic structures III, IV and VIII, cyclic structures V, VI and VII and any combination thereof. Any structure of FIG. 2 can be combined with any
    Petition 870190036739, of 17/04/2019, p. 42/76
    11/20 structure or structures including itself through any hydroxyl group functionality in the structure. The cyclic bonds of any basic cyclic structures of FIG. 2 can contain any structure or structures as part or parts of the connections. In FIG. 1 and FIG. 2, the numbers m, n, n ', o, p, q and r in each structure can, independently, be any numeral 0, 1, 2, ... 25. In FIG. 1 R and R 'are (CH2) n and n can, independently, be 1 or 0.
    [0019] In at least one application, Yankee's coating modifying agent comprises polyglycerol derivatives. Derivatives can be obtained by derivatizing polyglycerols with 1 to 22 carbon atoms. The modification includes, but is not limited to, alkylation, alkoxylation, esterification and similar modifications.
    [0020] In at least one application, the adhesive compositions of the present patent application are applied to the surface of a creping cylinder as a dilute aqueous solution. In one application, the aqueous solution includes from approximately 0.01 to approximately 10.0 weight percent of the polymers of the present application. In another application, the polymers of the present patent application are included in the aqueous solution in a concentration of approximately 0.05 to approximately 5.0 weight percent. In another application, the polymers of the present application are included in the aqueous solution in a concentration of approximately 0.1 to approximately 1.0 weight percent. Those skilled in the technique of creping adhesives will appreciate that the reason for this higher percentage of water in the mixture is partly based on the need to just deposit a very thin layer of adhesive on the
    Petition 870190036739, of 17/04/2019, p. 43/76
    12/20 creping cylinder, which, in one application, is most easily accomplished with a spray bar.
    [0021] In at least one application, the spray applications described above can be further improved by various means, for example, using spray bars designed for double or triple coverage, oscillating the spray bar and by recirculating the composition of the spray agent. diluted release from the spray boom outlet to improve mixing and reduce the possibility of separation.
    [0022] In at least one application, a release agent that is also in aqueous form is applied in the Yankee dryer together with the polymeric adhesive. The release agent provides lubrication between the Yankee dryer surface and the scraper blade used to crepe the Yankee dryer tissue paper. The release agent also allows the tissue paper to be released from the adhesive during the creping process. Representative release agents include release agents composed of naphthenic, paraffinic, vegetable, mineral or synthetic oil and emulsifying surfactants. In order to form stable aqueous dispersions, the release agent is typically formulated with one or more surfactants such as fatty acids, alkoxylated alcohols, alkoxylated fatty acids and the like. The release agent can be applied to the creping cylinder before or after the adhesive composition, or it can be added together with the adhesive for application to the creping cylinder.
    [0023] In at least one application, the adhesive compositions of the present patent application
    Petition 870190036739, of 17/04/2019, p. 44/76
    13/20 can also be used in combination with functional additives used in the art to improve the softness of the fabric or towel. Representative functional additives include organic quaternary salts with fatty chains of approximately 12 to approximately 22 carbon atoms including dialkyl imidazolinium quaternary salts, dialkyl diamidoamine quaternary salts, trimethylammonium monoalkyl quaternary salts, dialkyl dimethylammonium quaternary salts, monomial quaternary salts ethoxylated quaternary salts, dialkyl and trialkyl ester quaternary salts and similar substances. Additional suitable functional additives include polysiloxanes, quaternary silicones, organoreactive polysiloxanes, amino-functional polydimethylsiloxanes and similar substances.
    [0024] In at least one application, creping adhesives for preparing cremated paper include, but are not limited to the following: Polyamines, polyamides, polyamidoamines, amidoamine-epichlorohydrin polymers, polyethyleneimines, polyvinyl alcohol, vinyl alcohol copolymers, acetate polyvinyl, vinyl acetate copolymers, polyethers, polyacrylic acid, acrylic acid copolymers, cellulose derivatives, starches, starch derivatives, animal glue, vinylamine / vinyl alcohol cross-linked polymers as described in US Patent 5,374,334, glyoxalated acrylamide copolymers / diallyldimethyl acrylamide; the polymers described and claimed in US Patent 5,179,150; the polymers described and claimed in U.S. Patent 5,187,219; a mixture of approximately 0.1 to approximately 50 weight percent
    Petition 870190036739, of 17/04/2019, p. 45/76
    14/20 of a first polyamide-epialohydrin resin and from approximately 99.9 to approximately 50 weight percent of a second polyamide-epialohydrin resin, as described and claimed in U.S. Patent 6,277,242 B1 and creping cylinder adhesives halogen-free based on cross-linked polyaminoamide cationic polymers as described and claimed in US Patent 5,382,323.
    EXAMPLES [0025] The foregoing can be better understood by reference to the following examples, which are presented for purposes of illustration and are not intended to limit the scope of the present patent application.
    [0026] Several polyglycerol samples were characterized to determine their bulk viscosity and molecular weight including, Diglycerol and Polyglycerol-3 commercially available from Solvay Chemical International (Belgium) and synthesized materials PG-1 and PG-2 available from Nalco Company (Naperville, IL). A description of these samples is shown in Table 1 and shows that all samples had a higher viscosity and molecular weight than glycerol (PM = 92 g / mol). The bulk viscosity of the samples was measured by an AR2000 Rheometer (TA Instruments, New Castle, DE). The measurements were made on a rotating basis at a shear rate of 5 s -1 and 40 ° C. A 60 mm parallel plate was used with a 2000 pm span. For molecular weight measurements, all samples were analyzed using a CET method (size exclusion chromatography) and the reported molecular weights (PM) were the average molecular weights
    Petition 870190036739, of 17/04/2019, p. 46/76
    15/20 based on PEG / PEO calibration standards. Polyglycerols prepared by base condensation may contain lactic acid or lactate.
    Table 1. Descriptions and characterizations of the molecular weight of polyglycerol samples
    Sample Polyglycerol Type Viscosity (Pa-s) Pm * Glycerol - 0.26 92 Diglycerol Reticulated with Epi 2.3 140 Polyglycerol-3 Reticulated with Epi 6.6 200 PG-1 Base Condensation 35 320 PG-2 Base Condensation 130 540
    * Excludes glycerol monomer [0027] Example 1. General procedure for the production of polyglycerols: A reaction mixture of glycerol (500.0 parts) and NaOH or KOH solution (3 to 10% by weight of active in relation to total solids weight of the reaction) was stirred and heated gradually to 230 to 260 degrees Celsius under particular inert gas flow rates. The reaction mixture was stirred at this temperature for a desired reaction time (in hours) and samples of the process were collected after two hours and every one or two hours thereafter for product characterizations. Nitrogen flow rates at 0.2 to 8 moles of nitrogen per hour for each mole of glycerol or vacuum pressures below 760 mmHg were applied starting from the reaction time between 0 to 4 hours until the end of the reaction. Polyglycerol products were used for application directly or after dilution with water, with or without pH adjustment.
    [0028] Example 2. The volatility of polyglycerol samples was determined by thermogravimetry (TGA), Figure 3 is the coverage of weight loss curves by
    Petition 870190036739, of 17/04/2019, p. 47/76
    16/20
    TGA for glycerol in several polyglycerol samples. Table 2 lists the temperature at which 5% weight loss occurs in the samples. Weight loss of 5% glycerol occurs at 162 ° C, while weight loss of 5% of polyglycerol samples occurs at significantly higher temperatures. This indicates that all polyglycerol samples are less volatile than glycerol. Approximately 20-40 mg of samples were analyzed by TGA (TA Instruments, New Castle, DE) at a heating rate of 10 ° C / min. in an air atmosphere (flow rate: 90 ml / min.).
    Table 2. Weight loss temperature of 5% determined by
    TGA
    Sample Temperature (° C) Glycerol 162 Diglycerol 235 Polyglycerol-3 255 PG-1 192 PG-2 204
    [0029] Example 3. The lower volatility of polyglycerol compared to glycerol in dilute aqueous solutions is illustrated in Figure 4. As the modifier concentration becomes more diluted, the advantage of polyglycerol over glycerol becomes more apparent. At a modifier concentration of 1%, virtually 100% of the glycerol modifier is lost after drying at 105 ° C for 16.5 hours. In contrast, only 10% of the polyglycerol modifier is lost.
    [0030] Example 4. The plasticization properties of polyglycerol, when formulated as part of a Yankee dryer composition, were demonstrated from measurements of the glass transition temperature (Tg) and the cutting storage module (G '). The polymer Tg was measured by
    Petition 870190036739, of 17/04/2019, p. 48/76
    17/20
    Differential Scanning Calorimetry, and the G 'of the polymer film was measured by the rheometer. Table 3 shows the effect of modifiers on the Tg and G 'of PAE-based film. The results demonstrate that polyglycerol is as effective a plasticizer as glycerol. Polyglycerol reduced Tg in a similar way to glycerol, and polyglycerol modified PAE film is a softer film compared to unmodified film. A TA Q200 Differential Scanning Calorimeter (TA Instruments, New Castle, DE) was used to measure Tg. Polymer samples were prepared by molding films on a polypropylene plate. The samples were dried at 105 ° C in an oven overnight. Approximately 10-15 mg of sample was sealed in a DSC container with a lid. The sample was heated at a rate of 10 ° C / min. Tg was determined from the second scan using a half-height method. The cutting storage module G 'was measured by an AR2000 rheometer (TA Instruments, New Castle, DE). Polymer films were prepared by molding from a 5% (w / w) solution. The film was dried in an oven at 95 ° C overnight. The dry film was perforated with a mold (8 mm in diameter). The 8 mm disc was further dried in a vacuum oven at 110 ° C for two hours. The cutting storage module G 'was measured using an 8 mm parallel plate at 110 ° C and 1 Hz.
    Table 3. Effects of the modifiers on the glass transition temperature and on the PAE resin cutting storage module.
    Sample Tg (° C) G '(kPa) PAE 76 1500 PAE + Glycerol 55 510 PAE + PG-2 57 770 '
    Petition 870190036739, of 17/04/2019, p. 49/76
    18/20 [0031] Example 5. In order to compare the effect of polyglycerols and glycerol on adhesion, a coating and dry peeling test was performed. This test measured the force required to peel a strip of cotton glued to a heated metal plate. First, an adhesive composition was applied to the ECP metal plate by a coating rod No. 40. The adhesive applied to the plate had no more than 15% solids. The plate was heated to 100 ° C and a dry cotton strip was pressed against the plate by a 1.9 kg cylinder. Then, the metal plate was heated to 105 ° C and the strip was left to dry for 15 minutes. Then, the metal plate was attached to a test device and the tissue was removed from the plate at an angle of 180 ° at a constant speed. The test results shown in FIG. 5 demonstrate the effectiveness of the present patent application. The sample without modifier did not show adherence to the dry coating because as the PAE adhesive film dried, it became brittle and too hard for the cotton strip to adhere to. Although the glycerol modifier can make the film softer which has increased adhesion to the dry coating, FIG. 5 makes it clear that films containing polyglycerol showed superior adhesion to the dry coating compared to films containing glycerol as a modifier.
    [0032] These data also make it clear that because polyglycerol works as an effective plasticizer, even in a rare circumstance, a residual amount of glycerol would be present in a sample of polyglycerol-modified film, residual glycerol would not work effectively as a plasticizer for polyamidoamine / epialohydrin since the greater abundance and
    Petition 870190036739, of 17/04/2019, p. 50/76
    19/20 polyglycerol effectiveness would outweigh any effect of residual glycerol. In addition, FIG. 3 makes it clear that because polyglycerols are less volatile under certain conditions of use (for example, 100 to 162 degree environments) under these conditions, glycerol is not an effective plasticizer for polyamidoamine / epialohydrin resin because it evaporates while retained polyglycerols do not work as plasticizers.
    [0033] Although that patent application can be incorporated in many different ways, preferred applications of the present patent application are shown in the drawings and described in detail here. The present disclosure is an example of the principles of the present patent application and is not intended to limit the present patent application to the particular applications illustrated. All patents, patent applications, scientific publications and any other referenced materials mentioned here are incorporated by reference in their entirety. In addition, the present application for a patent covers any possible combination of any or all of the various applications described and incorporated herein.
    [0034] The above disclosure is intended to be illustrative and not exhaustive. This description will suggest many variations and alternatives for someone with common skill in this technique. All of these alternatives and variations are intended to be included within the scope of the claims where the term "comprising means" including, but not limited to. Those familiar with the technique can recognize others equivalent to specific applications
    Petition 870190036739, of 17/04/2019, p. 51/76
    20/20 described here whose equivalents are also intended to be covered by the claims.
    [0035] It is understood that all the variations and parameters disclosed here are to cover any and all of the subvariations summarized here, and each number between the outcomes. For example, a declared variation of “1 to 10 is considered to include any and all sub-variations between (and inclusive) the minimum value of 1 and the maximum value of 10; that is, all subvariations starting with a minimum value of 1 or more (for example 1 to 6.1), ending with a maximum value of 10 or less (for example, 2.3 to 9.4, 3 to 8, 4 to 7) and, finally, for each number 1, 2, 3, 4, 5, 6, 7, 8, 9 and 10 contained within the variation.
    [0036] This completes the description of the preferred and alternative applications of the present patent application. Those familiar with the technique may recognize other equivalents to the specific application described here whose equivalents are also intended to be covered by the appended claims.
    权利要求:
    Claims (14)
    [1]
    1. METHOD FOR CREATING A PAPER NETWORK, characterized by the steps of: a) applying a coating composition to a rotating creping cylinder, the coating composition having at least one adhesive agent, at least one release agent and at least least one polyglycerol; b) press the paper net against the creping cylinder to adhere the paper net to the creping cylinder; and c) dislodging the paper web from the creping cylinder using a scraper blade.
    [2]
    2. METHOD FOR CREATING A NET OF PAPER, according to claim number 1, characterized in that the coating composition remains plasticized at a temperature beyond the volatility limit of glycerol.
    [3]
    3. METHOD FOR CREATING A NET OF PAPER, according to claim number 1, characterized in that the polyglycerol is between 1 and 70% of the coating composition.
    [4]
    4. METHOD FOR CREATING A NET OF PAPER, according to claim number 1, characterized in that the coating composition has a glass transition temperature below 100 ° C.
    [5]
    5. METHOD FOR CREATING A PAPER NET according to claim number 1, characterized in that the coating composition is readily rewetable after the paper has been dislodged from the creping cylinder.
    [6]
    6. METHOD FOR CREATING A NET OF PAPER, according to claim number 1, characterized in that the polyglycerols are selected from the group consisting of: polyglycerol according to the formula:
    Petition 870190036739, of 17/04/2019, p. 53/76
    2/4

    mnp 0H t where m, n, o, p, q and q are equal to an integer between more than 0 and less than 25, the polyglycerol formed by the cross-linked glycerol with epichlorohydrin, base condensation polyglycerols, polymerization of glycidol-based monomers and any combination of them.
    [7]
    7. METHOD FOR CREATING A PAPER NET, according to claim number 1, characterized in that the polyglycerol structure is selected from the group consisting of: linear, branched, hyper-branched, dendritic, cyclic or any combination of them.
    [8]
    8. METHOD FOR CREATING A NET OF PAPER, according to claim number 1, characterized in that the polyglycerol has a molecular weight greater than 100 g / mol.
    [9]
    9. METHOD FOR CREATING A NET OF PAPER, according to claim number 1, characterized in that the coating also has polyaminoamide-epichlorohydrin (PAE) resins, polyamine-epichlorohydrin resins, polyacrylamides, polyvinylamines, polyvinylpyrrolidones, natural polymers, natural polymers derivatized, starch, guar gum, carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, functional additives, organic quaternary salts containing fatty chains of 12 to 22 carbon atoms, quaternary imidazolinium salts, quaternary dialkyl diamidoamine salts, quaternary monoalkyl salts
    Petition 870190036739, of 17/04/2019, p. 54/76
    3/4 trimethylammonium, quaternary salts of dialkyl dimethylammonium, quaternary salts of trialkyl monomethylammonium, quaternary ethoxylated salts, quaternary salts of dialkyl and trialkyl ester, polysiloxanes, quaternary silicones, organo-reactive polysiloxanes, polydimethylsilamines, polyamines epichlorohydrin, polyethyleneimines, polyvinyl alcohol, vinyl alcohol copolymers, polyvinyl acetate, vinyl acetate copolymers, polyethers, polyacrylic acid, acrylic acid copolymers, cellulose derivatives, starches, starch derivatives, animal glue, vinylamine crosslinked polymers / vinyl alcohol, glyoxalated acrylamide / diallyldimethyl acrylamide copolymers, halogen-free creping cylinder adhesives based on cross-linked polyaminoamide cationic polymers and any combination thereof.
    [10]
    10. “METHOD FOR CREATING A NET OF PAPER, according to claim number 1, characterized in that the coating composition also contains lactic acid or lactate salt.
    [11]
    11. “METHOD FOR CREATING A PAPER NET, according to claim number 1, characterized in that the coating also contains release agents, other modifiers (including phosphates) and functional additives.
    [12]
    12. “METHOD FOR CREATING A PAPER NET, according to claim number 1, characterized in that the coating composition contains polyglycerols, polyglycerol derivatives, glycerol-based polyols and any combination thereof.
    [13]
    13. “METHOD FOR CREATING A NET OF PAPER,
    Petition 870190036739, of 17/04/2019, p. 55/76
    4/4 according to claim number 1, characterized in that the release agent contains one selected from the group consisting of: release agents composed of naphthenic, paraffinic, vegetable, mineral or synthetic oil and emulsifying surfactants, release agents formulated with one or more surfactants with fatty acids, alkoxylated alcohols, alkoxylated fatty acids and any combination thereof.
    [14]
    14. “METHOD FOR CREATING A NET OF PAPER, according to claim number 1, characterized in that the coating composition is applied as an aqueous solution, an emulsion or a dispersion.
    类似技术:
    公开号 | 公开日 | 专利标题
    BR112012016478B1|2020-02-18|METHOD FOR CREATING A PAPER NET
    BRPI0916122B1|2019-02-05|&#39;&#39; creping adhesive composition and creping method &#39;&#39;
    TWI582290B|2017-05-11|Method of using aldehyde-functionalized polymers to increase papermachine performance and enhance sizing
    BRPI0621163B1|2019-04-24|COMPOSITION, ADHESIVE COMPOSITION OF WATER CROSSING AND METHOD OF CROSSING A PAPER NETWORK
    TW201247783A|2012-12-01|Anti-soiling agent composition
    BR112012012978B1|2019-08-06|ALDEIDE FUNCTIONALIZED POLYMERS WITH IMPROVED STABILITY AND METHOD OF PRODUCTION OF A MEDIUM, WHICH HAVE CELLULOSIC FIBERS
    BR0007708B1|2011-07-12|synthetic polymers capable of hydrogen bonding and containing polysiloxane moieties.
    BRPI0506686B1|2014-12-30|METHOD FOR IMPROVING WATER REMOVAL FROM A PAPER SHEET ON A PAPER MACHINE
    BRPI0613840A2|2011-02-15|method of corrugating a paper web and polymer composition having a ph of about 6.5 to about 8
    BR112012014455B1|2020-05-12|Paper sizing composition, method of preparing a stable sizing composition and paper sizing method
    BR112013031620B1|2020-06-02|PROCESS TO PRODUCE COATED PACKING MATERIAL AND PACKAGING MATERIAL WITH AT LEAST ONE LOCKING LAYER FOR HYDROPHOBUS COMPOUNDS
    BRPI0613467A2|2011-01-11|use of non-thermoset polyamidoamines as dry strength resins
    BRPI0707069B1|2019-01-02|modified curling adhesive composition, paper web curling method, and creped paper product
    CA2897187A1|2014-07-10|Additives with cloud points to improve efficiency of release agents
    BR112013026135B1|2020-05-26|PROCESS TO PRODUCE A POLYMER CONTAINING ACYLATED VINYLAMINE AND ITS APPLICATION AS AN ADDITIVE FOR PAPER MANUFACTURE
    WO2018200437A1|2018-11-01|Polysaccharide coatings with oxygen barrier properties
    TW200831741A|2008-08-01|Grease resistant formulations
    BRPI0714996A2|2013-08-13|Method of operation of a papermaking process
    ES2770589T3|2020-07-02|Creping adhesives and methods of preparing and using them
    WO2000039396A1|2000-07-06|Creping adhesives obtained by the reaction of polyamide and polyvinylalcohol with epichlorohydrin
    BR112015022102B1|2022-01-25|Sizing emulsion comprising a sizing agent, an emulsifier and an aqueous component, as well as a method for enhancing the sizing
    BR112020019764A2|2021-01-26|compositions and methods for treating a substrate and for improving the adhesion of an image to a treated substrate
    EP3805279A1|2021-04-14|Resin material, aqueous solution, and adhesive
    BR112016022167B1|2021-12-21|METHOD FOR THE PRODUCTION OF A MICROFIBRILLATED CELLULOSE SUSPENSION
    WO1999018290A1|1999-04-15|Method for making cellulose substrates grease-proof
    同族专利:
    公开号 | 公开日
    ES2631527T3|2017-08-31|
    EP2521814A2|2012-11-14|
    BR112012016478A2|2016-04-12|
    KR20120125242A|2012-11-14|
    EP2521814B1|2017-05-10|
    CN102695831B|2016-03-02|
    WO2011084996A2|2011-07-14|
    JP5715157B2|2015-05-07|
    US8101045B2|2012-01-24|
    US20110162811A1|2011-07-07|
    WO2011084996A3|2011-10-20|
    CA2786403C|2016-11-15|
    CN102695831A|2012-09-26|
    EP2521814A4|2015-07-29|
    JP2013516554A|2013-05-13|
    PL2521814T3|2017-10-31|
    MX2012007864A|2012-08-03|
    MX360374B|2018-10-31|
    KR101765358B1|2017-08-04|
    CA2786403A1|2011-07-14|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    DE2455327A1|1973-11-30|1975-06-12|Procter & Gamble|PROCESS FOR PRODUCING POLYGLYCERIN|
    DE3809882A1|1988-03-24|1989-10-05|Solvay Werke Gmbh|METHOD FOR PRODUCING POLYGLYCERINES|
    WO1991010368A1|1990-01-16|1991-07-25|The Dow Chemical Company|Low caloric fat substitutes, precursors of such substitutes and methods of making same|
    EP0505002A3|1991-03-19|1993-10-13|Shell Internationale Research Maatschappij B.V.|Method of preparing polyethercyclicpolyols|
    US5187219A|1991-08-22|1993-02-16|Nalco Chemical Company|Water soluble polyols in combination with glyoxlated acrylamide/diallyldimethyl ammonium chloride polymers as Yankee dryer adhesive compositions|
    US5179150A|1991-10-07|1993-01-12|Nalco Chemical Company|Polyvinyl alcohols in combination with glyoxlated-vinyl amide polymers as yankee dryer adhesive compositions|
    US5382323A|1993-01-08|1995-01-17|Nalco Chemical Company|Cross-linked poly as yankee dryer adhesives|
    US5374334A|1993-12-06|1994-12-20|Nalco Chemical Company|Class of polymeric adhesives for yankee dryer applications|
    JP3331069B2|1994-10-24|2002-10-07|花王株式会社|Diffusible absorbent paper|
    JP3331068B2|1994-10-24|2002-10-07|花王株式会社|Permeable absorbent paper|
    US5575891A|1995-01-31|1996-11-19|The Procter & Gamble Company|Soft tissue paper containing an oil and a polyhydroxy compound|
    CN1179193A|1995-02-15|1998-04-15|普罗克特和甘保尔公司|Method for enhancing bulk softeness of tissue paper and product therefrom|
    US5833806A|1995-04-25|1998-11-10|Hercules Incorporated|Method for creping fibrous webs|
    NZ286384A|1995-04-25|1998-05-27|Hercules Inc|Process and composition for creping paper to give desired texture, where the composition comprises polyamine/epihalohydrin resin adhesive and a plasticizer|
    JPH1128173A|1997-07-11|1999-02-02|Toshiyuki Ono|Clean toilet paper|
    US6547925B1|1997-07-21|2003-04-15|Kimberly-Clark Worldwide, Inc.|Method of applying chemical softening agents for making soft tissue|
    US6277242B1|2000-02-28|2001-08-21|Calgon Corporation|Creping adhesive containing an admixture of PAE resins|
    US7588660B2|2002-10-07|2009-09-15|Georgia-Pacific Consumer Products Lp|Wet-pressed tissue and towel products with elevated CD stretch and low tensile ratios made with a high solids fabric crepe process|
    US20040162367A1|2003-02-19|2004-08-19|Huntsman Petrochemical Corporation|Alkanolamine polymer salt additives for creping of fibrous webs|
    US7799167B2|2005-06-09|2010-09-21|Kawano Paper Co., Ltd.|Embossed crepe paper and its manufacturing method|
    US8293073B2|2005-06-30|2012-10-23|Nalco Company|Modified vinylamine/vinylformamide polymers for use as creping adhesives|
    US8066847B2|2005-12-29|2011-11-29|Nalco Corporation|Creping adhesives comprising blends of polyaminoamide epihalolhydrin resins and polyamides|
    US8753478B2|2005-12-29|2014-06-17|Nalco Company|Creping adhesives comprising blends of high and low molecular weight resins|
    WO2007092407A2|2006-02-06|2007-08-16|Cargill, Incorporated|Process for preparing polyglycerol and mixed ethers|
    JP2008006273A|2006-06-02|2008-01-17|Lion Corp|Tissue paper|
    US8357734B2|2006-11-02|2013-01-22|Georgia-Pacific Consumer Products Lp|Creping adhesive with ionic liquid|
    EP1930499A1|2006-12-08|2008-06-11|Cognis IP Management GmbH|Tissue paper comprising a softening lotion|
    US9284625B2|2007-11-20|2016-03-15|Nalco Company|Use of polyols as scale control reagents in the mining processes|
    US9290620B2|2009-10-21|2016-03-22|Nalco Company|Production and composition of glycerol based polyols|
    US8101045B2|2010-01-05|2012-01-24|Nalco Company|Modifying agent for yankee coatings|US9266301B2|2005-06-30|2016-02-23|Nalco Company|Method to adhere and dislodge crepe paper|
    US8884049B2|2009-10-21|2014-11-11|Nalco Company|Glycerol based polymer surface active chemistry and production|
    IN2014DN08895A|2012-05-31|2015-05-22|Nalco Co|
    US9416490B2|2010-03-10|2016-08-16|Nalco Company|Cross-linked glycerol based polymers as digestion aids for improving wood pulping processes|
    US8101045B2|2010-01-05|2012-01-24|Nalco Company|Modifying agent for yankee coatings|
    US20110201534A1|2010-02-12|2011-08-18|Jennifer Beth Ponder|Benefit compositions comprising polyglycerol esters|
    US20110201532A1|2010-02-12|2011-08-18|Jennifer Beth Ponder|Benefit compositions comprising crosslinked polyglycerol esters|
    JP5475497B2|2010-02-22|2014-04-16|出光興産株式会社|Water-based heat treatment liquid composition|
    WO2014105489A1|2012-12-28|2014-07-03|Nalco Company|Anionic lipophilic glycerol-based polymers for organic deposition control in papermaking processes|
    US8709209B2|2010-03-10|2014-04-29|Nalco Company|Anionic lipophilic glycerol-based polymers for organic deposition control in papermaking processes|
    US8728275B2|2012-07-27|2014-05-20|Ecolab Usa Inc.|Glycerol-based polymers for reducing deposition of organic contaminants in papermaking processes|
    US9656914B2|2013-05-01|2017-05-23|Ecolab Usa Inc.|Rheology modifying agents for slurries|
    WO2015016350A1|2013-08-02|2015-02-05|星光Pmc株式会社|Adhesive for crepe and method for manufacturing crepe paper|
    US9034145B2|2013-08-08|2015-05-19|Ecolab Usa Inc.|Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention, wet strength, and dry strength in papermaking process|
    US9303360B2|2013-08-08|2016-04-05|Ecolab Usa Inc.|Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention in papermaking process|
    US9410288B2|2013-08-08|2016-08-09|Ecolab Usa Inc.|Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention in papermaking process|
    EP3080224B1|2013-12-10|2021-06-23|Buckman Laboratories International, Inc|Adhesive formulation and creping methods using same|
    US9243365B2|2013-12-20|2016-01-26|Georgia-Pacific Chemicals Llc|Release aids with adjustable cloud points for creping processes|
    US9567708B2|2014-01-16|2017-02-14|Ecolab Usa Inc.|Wet end chemicals for dry end strength in paper|
    US9834730B2|2014-01-23|2017-12-05|Ecolab Usa Inc.|Use of emulsion polymers to flocculate solids in organic liquids|
    CA2970314C|2014-12-12|2019-09-24|Solenis Technologies, L.P.|Method of producing a creping paper and the creping paper thereof|
    US10570347B2|2015-10-15|2020-02-25|Ecolab Usa Inc.|Nanocrystalline cellulose and polymer-grafted nanocrystalline cellulose as rheology modifying agents for magnesium oxide and lime slurries|
    CN106283864A|2016-08-23|2017-01-04|山东太阳生活用纸有限公司|A kind of modified polyethyleneimine glues cylinder agent|
    EP3555177A1|2016-12-14|2019-10-23|Ecolab USA, Inc.|Quaternary cationic polymers|
    BR112019019677A2|2017-03-21|2020-04-22|Solenis Technologies, L.P.|composition and method of producing a creping paper and creping paper of the same|
    WO2018180158A1|2017-03-29|2018-10-04|株式会社メンテック|Coating film modifier for creping|
    CN110997593A|2017-07-17|2020-04-10|埃科莱布美国股份有限公司|Rheology modifier for slurries|
    CN108166311A|2017-10-24|2018-06-15|苏州丰倍生物科技有限公司|A kind of plant type paper anti-adhesion agent and preparation method thereof|
    JP2019150136A|2018-02-28|2019-09-12|大王製紙株式会社|Tissue paper|
    US20210198848A1|2018-06-12|2021-07-01|Ecolab Usa Inc.|Quaternary cationic surfactants and polymers for use as release and coating modifying agents in creping and tissue papers|
    CN110862767A|2019-11-30|2020-03-06|谢裕祥|Low-speed cylinder spraying agent for cylinder paper machine|
    CN112301791A|2020-08-21|2021-02-02|浙江杭化新材料科技有限公司|Preparation method of vat sticking agent for household paper|
    法律状态:
    2018-04-10| B06F| Objections, documents and/or translations needed after an examination request according art. 34 industrial property law|
    2019-02-19| B06T| Formal requirements before examination|
    2019-12-17| B09A| Decision: intention to grant|
    2020-02-18| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 05/01/2011, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    US12/652,059|US8101045B2|2010-01-05|2010-01-05|Modifying agent for yankee coatings|
    US12/652,059|2010-01-05|
    PCT/US2011/020213|WO2011084996A2|2010-01-05|2011-01-05|Improved modifying agent for yankee coatings|
    [返回顶部]